Most of the 57 people on board the bus were students on the Erasmus programme who were returning to Barcelona after a trip to a fireworks festival.
Photographs from the scene show a white roofed coach lying on its side, surrounded by emergency vehicles.
The accident occurred near Freginals, 150km (93 miles) south of Barcelona.
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Image caption The bus overturned after hitting a car travelling in the opposite direction

Image caption The driver of the coach survived the crash
The nationalities of those killed and the 43 people injured have not been confirmed, nor has the cause of the accident.
But Jordi Jane, Catalonia's regional interior minister said the driver of the coach "hit the railing on the right and swerved to the left so violently that the bus veered onto the other side of the highway".
The bus then hit a vehicle coming in the opposite direction, injuring two people inside.
"There were students on board, many of them foreign students studying in Catalonia and in Barcelona who had travelled to Valencia for the Fallas and were returning," Jane added.
The driver of the bus survived the collision and has been taken to a local police station.
Erasmus programme
European Union student exchange programme set up in 1987
Named after Dutch philosopher Desiderius Erasmus of Rotterdam
For many participants, Erasmus is their first time living and studying in another country

Image caption Players of Espanyol and Athletic Bilbao observed a minute of silence in tribute to the victims of the crash
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